4-Chloro-N-(3-methyl­phen­yl)benzamide

نویسندگان

  • Vinola Z. Rodrigues
  • Marek Fronc
  • B. Thimme Gowda
  • Jozef Kožíšek
چکیده

In the title compound, C(14)H(12)ClNO, the meta-methyl substituent in the aniline ring is positioned anti to the N-H bond. The dihedral angle between the rings is 12.4 (1)°. The crystal structure is stabilized by inter-molecular N-H⋯O hydrogen bonds, which link the mol-ecules into C(4) chains running along the c-axis direction.

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منابع مشابه

N-(4-Methyl­phen­yl)benzamide

The structure of the title compound, C(14)H(13)NO, resembles those of N-(2-chloro-phen-yl)benzamide, 2-chloro-N-phenyl-benzamide, N-(2,3-dichloro-phen-yl)benzamide, N-(3,4-dichloro-phen-yl)benzamide and 2-chloro-N-(2-chloro-phen-yl)benzamide with similar bond parameters. The benzene and methylphenyl rings have a dihedral angle of 63.41 (5)°, while the amide group makes a dihedral angle of 20.5 ...

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4-Chloro-2-hy­droxy-N-(4-methyl­phen­yl)benzamide

In the title compound, C(14)H(12)ClNO(2), the dihedral angle between the aromatic rings is 14.87 (11)° and an intra-molecular N-H⋯O hydrogen bond generates an S(6) ring. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds, generating C(6) chains propagating along the c-axis direction.

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2-Chloro-N-(4-methyl­phen­yl)benzamide

In the title compound, C(14)H(12)ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C=O bond. The benzoyl and aniline benzene rings are tilted relative to each other by 82.8 (1)°. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into infinite chains running along the c-axis direction.

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2-Chloro-N-(2-methyl­phen­yl)benzamide

In the title compound, C(14)H(12)ClNO, the two aromatic rings are almost coplanar, making a dihedral angle of 4.08 (18)°. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into infinite chains running along the a axis.

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3-Chloro-N-(3-methyl­phen­yl)benzamide

In the mol-ecular structure of the title compound, C(14)H(12)ClNO, the meta-Cl atom in the benzoyl ring is positioned syn to the C=O bond, while the meta-methyl group in the aniline ring is positioned anti to the N-H bond. The two aromatic rings make a dihedral angle of 77.4 (1)°. In the crystal, the molecules are linked by N-H⋯O hydrogen bonds, forming C(4) chains propagating in [010].

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011